IRON(III) PHOSPHATE CATALYZED SYNTHESIS OF ß-AMIDO
CARBONYL COMPOUNDS
Farahnaz K. Behbahani, Sara Naeini, Saeed Suzangarzadeh.
Abstract
Aldehydes have been used in a one-pot reaction with enolizable ketones, acetonitrile, benzonitrile and acetyl chloride in the presence of
FePO4 at room temperature to form the corresponding β-acetamido ketones in very good yields. Three new compounds and rare β-amido
ketones are reported additionally. The use of readily available FePO4 as a catalyst renders this process quite simple and convenient.
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