| Original Article | 
|  |
ECB. 2016; 5(11): 495-500 1,2-HYDROGEN MIGRATION IN AMINOALKYL RADICALS IN
AMINATION REACTIONS OF α-OLEPHINS T. A. Aslanov, E. T. Aslanova, N. R. Bektashi, A. H. Azizov, D. R. Nurullayeva. Abstract | | | | The amination of α-olefins (C4-C7) in the NН2OH·HCl-TiCl3 oxidation-reduction system was investigated and a number of mono- and
diamines were prepared. It has been found that in the attack of NH2-radical to olefin a hydrogen migration from first carbon to second one
takes place. It has been shown that in the reaction products, besides the desired individual amines, telomers, the molecular masses of which
are approximately within the ranges of Мn = 460-800, were also detected.
Key words: α-olefins, 1,2-hydrogen migration, diamines, telomers.
|
|
|
|
