The problems concerned with the processes of template synthesis of 3d-element metal aza- and thiazamacrocyclic complexes that happen in
nanoreactors on the basis of thin films metal hexacyanoferrate(II)-gelatin-immobilized matrix implants under their contact with water
solutions containing various (N,O,S)-donor atomic ligands and organic compounds having one or two carbonyl groups have been
considered. It was noted that, in a series of cases, the variety of metal macrocyclic compounds obtained at template synthesis in such
specific conditions considerably differs from that of metal macrocycles formed at the conditions traditional for chemical synthesis.
Key words: azamacrocyclic metal chelate; thiaazamacrocyclic metal chelate; thin film; molecular structure.
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