Abstract

The study of mercury (Hg) and selenium (Se) bioaccumulation in fish is of great importance in order to evaluate the extent of mercury and selenium contamination in the aquatic environment and their possible health risk for humans, considering their antagonistic interactions. Total selenium, total mercury, and methyl mercury were determined in one hundred and ninety-nine (199) fish samples belonging to twenty-six (26) different species at various trophic levels in the Volta Lake in Ghana. Total mercury and methyl mercury were determined with a Direct Mercury Analyzer and Selenium with ICP-MS. The concentrations of total mercury, methyl mercury, and total selenium in fish were related to the preferred prey and their bioavailability in the freshwater environment. There was an increase in concentration of total mercury, methyl mercury and total selenium at successive higher trophic levels of the food chain suggesting that they all biomagnified throughout the food chain. There were statistically significant correlations (p

Key words: Total mercury, methylmercury, total selenium, fish species, mercury–selenium relationship.